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Reactivity in confined spaces / edited by Ross S. Forgan and Gareth O. Lloyd. - 1 online resource (xx, 469 pages) : illustrations (some color). - - Monographs in supramolecular chemistry ; no. 31 . - Monographs in supramolecular chemistry ; 31. .

Includes bibliographical references and index.

Macrocycles, catenanes and rotaxanes / N. H. Evans -- Catalytic strategies within the confined spaces of coordination cages / R. L. Spicer and P. J. Lusby -- Light-induced processes in coordination cages / Thomas Comerford, Eli Zysman-Colman and Michael D. Ward -- Stabilising reactive intermediates in cages / J. A. Robison and I. A. Riddell -- Reactivity in a self-assembled organic host / Carmine Gaeta, Carmen Talotta, Margherita De Rosa, Pellegrino La Manna, Annunziata Soriente and Placido Neri -- Properties and reactivities of metal complexes within organic nanocontainers / G. Borsato, F. Fabris and A. Scarso -- Catalysis at the confined interface of supramolecular gels / R. Marti-Centelles and B. Escuder -- Catalysis in confined space : relationship between metal-organic frameworks and discrete coordination cages / S. Pullen and G. H. Clever -- Solid/gas reactivity of organometallic species in confined spaces / Hellen Videa and Antonio J. Mart�inez-Mart�inez -- Topochemistry meets supramolecular chemistry : opportunities for targeted organic synthesis in molecular crystals / Gonzalo Campillo-Alvarado, Changan Li and Leonard R. MacGillivray -- Stabilising and characterising homogeneous catalysts in MOFs / Sarah L. Griffin, Georgia R. F. Orton, Rosemary J. Young, Christopher J. Sumby, Christian J. Doonan and Neil R. Champness -- Biomimetic metal-organic frameworks : construction and catalytic performance / Xiaoliang Wang and Shengqian Ma -- Catalytic nanoparticles in metal-organic frameworks / J. King and P. �A. Szil�agyi -- Atomically precise metal clusters in confined spaces of metal-organic frameworks / D. Armentano and E. Pardo.

"The chemistry that occurs within confined spaces is the product of a collection of forces, often beyond the molecule, and is not easily ascribed to singular factors. There is a breadth of material types that can define a confined space (e.g. macrocycles, interlocked molecules, porous and non-porous crystals, organic and inorganic/coordination cages) which are rarely discussed together. Studies of supramolecular entities in the solution and solid states are also not often compared in the same discussion, even though the concepts are often similar or can be easily transferred between the two. Chapters in this book combine classical host-guest chemistry with catalysis, reactivity, and modern supramolecular chemistry. They cover the many different technologies used to describe and understand reactivity in confined spaces in one accessible title. With contributions from leading experts, Reactivity in Confined Spaces will be relevant for graduate students and researchers working in supramolecular chemistry, both organic- and inorganic-based, homogeneous and heterogeneous catalysis, polymer chemistry, and materials science in general"--Page 4 of cover.

ISBN: 9781788019705 (PDF ebook) 1788019709 (PDF ebook) 9781788019712 (ebook) 1788019717 (ebook)

Source: 5787:5631 Royal Society of Chemistry http://www.rsc.org/spr

Nat. Bib. No.: GBC196711 bnb

Nat. Bib. Agency Control No.: 020226923 Uk

Subjects--Topical Terms:
Chemical reactions.
Supramolecular chemistry.
Chimie supramol�eculaire.
Supramolecular chemistry
Chemical reactions

LC Class. No.: QD501 / .R393 2021

Dewey Class. No.: 541.39