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019 _a1252850096
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020 _a9781839163623
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020 _z9781839161650
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020 _z1839161655
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035 _a2937154
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035 _a(OCoLC)1254050766
_z(OCoLC)1252850096
_z(OCoLC)1253680036
037 _a6213:6055
_bRoyal Society of Chemistry
_nhttp://www.rsc.org/spr
050 4 _aQD549
_b.R44 2021
050 4 _aRS201.N35
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082 0 4 _a541.345
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082 0 4 _a620.5
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049 _aMAIN
245 0 0 _aReducing agents in colloidal nanoparticle synthesis /
_cedited by Stefanos Mourdikoudis.
264 1 _aLondon, UK :
_bRoyal Society of Chemistry,
_c[2021]
264 4 _c�2021
300 _a1 online resource (xvi, 465 pages) :
_billustrations.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_2rdaft
490 1 _aNanoscience & nanotechnology series ;
_vvolume 50
504 _aIncludes bibliographical references and index.
520 _aNanoparticles can be synthesised via a number of methods, including chemical vapor deposition, ball milling, laser ablation, thermal decomposition and chemical reduction. Chemical reduction is usually preferred, due to its ease and cost-effectiveness. There are several types of compound used as reducing agents in nanoparticle synthesis, and one recent development is the use of biological entities as environmentally friendly reductants. This book will highlight the role of reducing agents in the chemical synthesis of nanoparticle systems, presenting the main categories of reducing agents, which vary on reactivity, selectivity, availability and toxicity. It will provide a comprehensive presentation of both modern and more conventional types of reagents. Emphasis will be given on the presentation not only of the functionality, but also of all the different advantages and limitations of each kind of reducing agent. With contributions from global experts, this title will be appropriate for graduate students and researchers in nanochemistry, colloidal synthesis, inorganic chemistry, organometallic chemistry, chemical engineering, physical chemistry, materials science, biology and physics.
505 0 _aIntro -- Half Title -- Series -- Title -- Copyright -- Preface -- Contents -- Chapter 1 Reducing Agents in Colloidal Nanoparticle Synthesis -- an Introduction -- 1.1 Historical Point of View -- 1.2 Polyols -- 1.3 Redox Potential on Polymer Nanoparticles -- 1.4 Biological Materials (Plant and Leaf Extracts) -- Nanoparticle Phytosynthesis -- 1.5 Miscellaneous Reductants -- 1.5.1 Bacteria -- 1.5.2 Fungi -- 1.5.3 Algae -- 1.5.4 Proteins -- References -- Chapter 2 Role of Alcohols in Colloidal Nanoparticle Synthesis -- 2.1 Introduction -- 2.2 Advantages of Alcohols as Solvent
505 8 _a2.3 Choice of Alcohol -- 2.4 Dependence of Shape and Structure of Nanoparticles on Type of Alcohol -- 2.5 Microwave-assisted Synthesis of Colloidal Nanoparticles in Alcohol Solvent -- 2.6 Influence of Surfactants and Reductants in Nanoparticles Synthesis in Alcohol Solvents -- 2.7 Role of Alcohols as Reducing Agents in Heterogeneous Media -- 2.8 Conclusions -- References -- Chapter 3 Polyols as a Toolbox for the Preparation of Inorganic-based Nanostructures -- 3.1 Introduction -- 3.2 Polyol Aspects -- 3.3 Redox System -- 3.4 The Role of Polyol-Metal Intermediate Complexes
505 8 _a3.5 The "Spare" Benefit of the Polyol Process: Coating -- 3.6 The Various Compositions of Nanoparticles Synthesized in Polyol Media -- 3.6.1 Metallic Nanoparticles -- 3.6.2 Oxide Nanoparticles -- 3.6.3 Bimetallic Nanoparticles -- 3.7 Conclusions -- References -- Chapter 4 Role of Phenols and Phenol Derivatives in the Synthesis of Nanoparticles -- 4.1 Introduction -- 4.1.1 Phenol Derivatives and Their Chemical and Physical Properties -- 4.1.2 Chelating Properties of Phenols -- 4.1.3 Polyphenols in Nature and Their Reducing and Capping Properties -- 4.1.4 Synthesis of Au Nanoparticles with Phenols
505 8 _a4.1.5 Synthesis of Ag Nanoparticles with Phenols -- 4.1.6 Synthesis of Pd Nanoparticles with Phenols -- 4.2 Synthesis of Metal Oxide Nanoparticles with Phenols and Phenol Derivatives -- 4.3 Conclusion and Future Perspectives -- References -- Chapter 5 Gases -- 5.1 Introduction -- 5.2 Hydrogen -- 5.2.1 Metal Salts -- 5.2.2 Organometallic and Metal-Organic Compounds -- 5.3 Carbon Monoxide -- 5.3.1 Ligand Displacement Without Reduction -- 5.3.2 Mild Reducing Agent for Reaction Monitoring -- 5.3.3 Homogeneously Catalyzed Ligand Carbonylation -- 5.3.4 CO as Shape-directing Agent
505 8 _a5.4 Risks Associated with the Use of H2 and CO and Safety-related Best Practices -- 5.5 Conclusions -- Acknowledgements -- References -- Chapter 6 Amines and Amine-boranes -- 6.1 Introduction -- 6.2 Alkyl and Aryl Amines -- 6.2.1 Noble Metals -- 6.2.2 Magnetic Metals -- 6.2.3 Semiconductors and Metalloids -- 6.3 Hydrazine -- 6.4 Amine-boranes -- 6.4.1 The Case of Noble Metals -- 6.4.2 The Case of Magnetic Metals -- 6.4.3 The Case of Semiconductors and Metalloids -- 6.5 Polymeric Amines -- 6.6 Conclusion -- References -- Chapter 7 Acids -- 7.1 Introduction -- 7.2 Carboxylic Acids
588 0 _aOnline resource; title from digital title page (viewed on June 15, 2021).
590 _aAdded to collection customer.56279.3
650 0 _aNanoparticles
_xSynthesis.
_916934
650 0 _aReduction (Chemistry)
_916935
650 6 _aNanoparticules
_xSynth�ese.
_916936
650 6 _aR�eduction (Chimie)
_916937
650 7 _aReduction (Chemistry)
_2fast
_916935
700 1 _aMourdikoudis, Stefanos,
_eeditor.
_916938
776 0 8 _iPrint version:
_tReducing agents in colloidal nanoparticle synthesis.
_dCambridge : Royal Society of Chemistry, [2021]
_z9781839161650
_w(DLC) 2021443049
_w(OCoLC)1197722153
830 0 _aRSC nanoscience & nanotechnology ;
_v50.
856 4 0 _3EBSCOhost
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