Gibbs Energy and Helmholtz Energy [electronic resource] : Liquids, Solutions and Vapours.

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Intro -- Halftitle -- Title -- Copyright -- Foreword -- Preface -- Contents -- Chapter 1 Gibbs Energy and Helmholtz Energy: Introduction, Concepts and Selected Applications -- 1.1 Introduction -- 1.2 Thermodynamic Fundamentals -- 1.3 More Thermodynamics and Selected Applications -- 1.3.1 Real Fluids: Fundamentals -- 1.3.2 Residual Properties, Fugacities and Fugacity Coefficients -- 1.3.3 Empirical (Thermal) Equations of State and More: Selected Comments -- 1.3.4 Property Changes on Mixing and Excess Properties -- 1.4 Concluding Remarks, Future Directions and Acknowledgements -- Appendix

References -- Chapter 2 Low-pressure Solubility of Gases in Liquids -- 2.1 Introduction -- 2.2 Thermodynamics -- 2.2.1 Fundamentals -- 2.2.2 Experimental Reality: Subtleties of Approximation -- 2.3 Selected Results -- 2.4 Concluding Remarks -- References -- Chapter 3 Assembly of Hard Spheres in Liquid Water -- 3.1 Introduction and Statement of the Problem -- 3.2 Model Solvation Free Energies -- 3.2.1 Small Solutes -- 3.2.2 Large Solutes -- 3.3 Detailed Model Free Energy for Assembly -- 3.4 Driving Forces for Assembly -- 3.5 Perspective and Implications -- Appendix -- Acknowledgements.

References -- Chapter 4 Excess Molar Gibbs Energies: Related Properties and Formalisms Using DISQUAC -- 4.1 Introduction -- 4.2 Some Equations and Models -- 4.2.1 Vapour-Liquid Equilibria Under Isothermal Conditions -- 4.2.2 Solid-Liquid Equilibria -- 4.2.3 Liquid-Liquid Equilibria -- 4.2.4 The Concentration-Concentration Structure Factor -- 4.2.5 Kirkwood-Buff Integrals -- 4.2.6 DISQUAC -- 4.3 Phase Equilibria Results -- 4.3.1 Vapour-Liquid Equilibria -- 4.3.2 Solid-Liquid Equilibria -- 4.3.3 Liquid-Liquid Equilibria -- 4.4 Results for SCC(0) and Kirkwood-Buff Integrals.

4.4.1 1-Alkanol (1) or Polar Compound (1) + Heptane (2) -- 4.4.2 1-Alkanol (1) + Polar Compound (2) -- 4.5 Situation of Systems in the GEm versus HEm Diagram -- 4.6 Conclusion -- Appendix -- References -- Chapter 5 Simultaneous Determination of Equilibrium Constants, Enthalpy Changes and Stoichiometries by Titration Calorimetry -- 5.1 Introduction -- 5.2 History -- 5.3 Data Analysis -- 5.4 Operating Parameters -- 5.5 Instrument Calibration -- 5.6 Statistical Error Analysis of the Inferred Parameters -- 5.7 Method for Optimizing Operating Conditions -- 5.8 Typical Applications in Biophysics

5.8.1 Advantages of Isothermal Titration Calorimetry (ITC) -- 5.8.2 Food Science -- 5.8.3 Nutritional Science -- 5.8.4 Pharmaceuticals -- References -- Chapter 6 Solvation Free Energy by 3D-RISM-KH Theory -- 6.1 Introduction -- 6.1.1 3D-RISM-KH Theory -- 6.2 Solvation Free Energies from the 3D-RISM-KH Theory -- 6.2.1 Hydration Free Energy -- 6.2.2 Solvation Free Energies in Non-aqueous Solvents -- 6.2.3 Overall Performance of the 3D-RISM-KH Theory in Predicting SFE -- 6.3 Molar Partition Coefficients Using the 3D-RISM-KH Theory -- 6.4 Conclusion -- Acknowledgements -- References

Chapter 7 Calculation Itinerary to Check the Quality of Vapour-Liquid Equilibrium Data.

This book contains the latest information on all aspects of the most important chemical thermodynamic properties of Gibbs energy and Helmholtz energy, as related to fluids.

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