Porphyrin-based Supramolecular Architectures [electronic resource] : From Hierarchy to Functions.

Description based upon print version of record.

Intro -- Title -- Copyright -- Contents -- Chapter 1 Structural Design of Porphyrin-based MOFs -- 1.1 Introduction -- 1.2 Carboxylate Linkers -- 1.2.1 Tetratopic Carboxylate Linkers -- 1.2.2 Ditopic Carboxylate Linkers -- 1.2.3 Hexatopic Carboxylate Porphyrin Linkers -- 1.2.4 Octatopic Carboxylate Porphyrin Linkers -- 1.3 Pyridinyl Porphyrin Linkers -- 1.3.1 Tetratopic Pyridinyl Linkers -- 1.3.2 Ditopic Pyridinyl Linkers -- 1.4 Azole Porphyrin Linkers -- 1.4.1 Tetratopic Pyrazolate Linkers -- 1.4.2 Tetratopic Tetrazole Linkers -- 1.4.3 Ditopic Imidazole Linkers -- 1.5 Other Tetratopic Linkers

1.5.1 Phosphonate Porphyrin Linkers -- 1.5.2 Cyanoporphyrins -- 1.5.3 Hydroxy Porphyrins -- 1.6 Porphyrin Linkers -- References -- Chapter 2 Metalloporphyrins as Building Blocks to Supramolecular Architectures with Catalytic Functions -- 2.1 Introduction -- 2.2 Self-assembled Porphyrin Structures in Catalysis -- 2.2.1 Confined Space Hydroformylation Catalysis -- 2.2.2 Catalyst Stabilization and Size Selectivity in Confined Space -- 2.2.3 Catalyst Stabilization and Lowering Overpotential in Confined Space -- 2.3 Supramolecular Light Harvesting Porphyrin Assemblies -- Chromophores

2.3.1 Chromophore Organization -- 2.3.2 Supramolecular Porphyrin Antennae -- 2.3.3 Light Harvesting Using Supramolecular Polymer Assemblies of Porphyrins -- 2.3.4 Supramolecular Scaffolds Pre-organizing Porphyrins -- 2.4 Supramolecular Charge-separation with Porphyrin Assemblies -- Charge-separation -- 2.4.1 Discrete Supramolecular Charge-separation Assemblies -- 2.4.2 Integrated Antenna/Charge-separation Assemblies -- 2.5 Integrated Supramolecular Light-harvesting Porphyrin Catalyst Assemblies -- Chromophore-Catalyst Assemblies -- 2.5.1 Supramolecular Photochemical Proton Reduction

2.5.2 Supramolecular Photochemical Water Oxidation -- 2.6 Conclusion -- References -- Chapter 3 Design of Porphyrinic Metal-Organic Frameworks -- 3.1 Introduction -- 3.2 Symmetry-guided Coordination Networks with Porphyrin Building Units -- 3.2.1 Pyridyl-based Porphyrin Coordination Networks -- 3.2.2 Self-assembly of Porphyrinic Metal-Organic Frameworks with Secondary Building Units -- 3.2.3 Rod-packing Secondary Building Unit-based Porphyrinic Metal-Organic Frameworks -- 3.3 Mixed-linker Approach for New Porphyrin-based Metal-Organic Frameworks

3.4 Other Noteworthy Porphyrin-based Coordination Networks -- 3.4.1 Coordination Networks Based on Sulfonate and Phosphonate-containing Porphyrin -- 3.4.2 Self-assembly of Polyoxometalate-based Porphyrinic Coordination Networks -- 3.5 Conclusions and Future Directions -- Abbreviations -- Acknowledgements -- References -- Chapter 4 Heterogeneous Catalysis of Porphyrin-based MOFs -- 4.1 Introduction -- 4.2 Catalysis of Cycloaddition Reactions -- 4.3 Catalysis of Reactions Involving Alkanes, Alkenes, and Alkynes -- 4.4 Other Reactions Catalyzed by Por-MOFs -- 4.5 Conclusion -- References

Chapter 5 Porphyrin-encapsulating Metal-Organic Materials as Solid-state Mimics of Heme Enzymes.

Porphyrin-based Supramolecular Architectures focuses on recent developments in the field, emphasising cutting-edge research and the diverse range of applications.

WorldCat record variable field(s) change: 050, 082, 650